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Being new to the hobby Im sure theres a lot of cards Im simply unaware of and dont have a huge collection to date, so a small pool to select from but would say the FA Blastoise ex from the 20th Anniversary set is probably whats surprised me most from purchase expectations (bought mostly due to price) to how it looks in person

And as has been suggested by the aforementioned list of most valuable Pokmon TCG cards, this pattern generally repeats, meaning Secret Rares are consistently more valuable than other cards in this way

You can usually earn more if you opt for store credit

However, these anti-synergies always sound worse in theory than they are in practice (see the current build of UR Murktide), particularly giving the turbo-fueling that DRC provides